Picture of PHI5000 Versa Probe III XPS
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X-ray photoelectron spectroscopy (XPS), or electron spectroscopy for chemical analysis (ESCA), is a material characterisation technique that provides elemental and chemical information for solid sample with the analysing depth in few atomic layers. XPS is an instrument in surface science for thin films, coatings and native oxide layers study. Wide range of materials like metals, semiconductors, ceramics, polymers and composite materials, regardless of electrical conductivity, can be analysed. A brief outline about an XPS process include X-ray irradiation, photoelectron excitement and kinetic energy detection of the emitted electron. Characteristic energies of the excited photoelectrons from different electron shells of elements are located at different energy positions as peaks along the XPS spectrum, with which the chemical composition and the chemical state of the individual element can be determined. The precision of an analysing area is in micron, depends on the size of the adjustable focused X-ray beam.

This XPS is within the infrastructure of Chalmers Materials Analysis Laboratory (CMAL) and is hosted by the Department of Industrial and Materials Science. Together with the traditional spectrometric and depth profiling functions, large and small area X-ray mapping and angle-resolving analysis are the two other features for fine features imaging and non-destructive ultra-thin films analyses.

Should you seek help, training, or further information, please contact Associate Professor Emmy Yu Cao (Tel.: 031-772-1252; Email: yu.cao@chalmers.se), or Dr. Eric P.L. Tam (Tel: 031-772-1253; Email: eric.tam@chalmers.se) at the Department of Industrial and Material Science.

Tool name:
PHI5000 Versa Probe III XPS
Category:
Surface Analysis
Manufacturer:
ULVAC-PHI, Inc.
Model:
PHI5000 VersaProbe III Scanning X-ray Microprobe

Sample preparation:

  • Sample dimension: Height limitation 7 mm; 15 mm in diameter for the 25 mm platen; 50 mm in diameter for the 60 mm platen.
  • Handle the samples and the needed tools with gloves.
  • Sample must be dried solid.
  • No volatile substance is allowed.
  • Sample can be cleaned with ethanol/isopropanol before introduction.
  • Sample should NEVER be cleaned by ACETONE in the final step.
  • Big sample can be covered by molybdenum (Mo) mask and fastened with screws.
  • Small sample is recommended to stick on the double-sided tape or covered with copper tape.

Suggested pumping time:

  • Metal / Alloy (15 - 30 minutes)
  • Semiconductor (15 - 30 minutes)
  • Ceramics (60 - 120 minutes)
  • High dense polymer (> 120 minutes)
  • Porous materials (Overnight)

Indication: When V1 is opened for the sample introduction, the pressure in the Main Chamber should be around or better than 3.0 x 10-6 Pa.

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